Linking groundwater pollution to the decay of 15th-century sculptures in Burgos Cathedral (northern Spain).
Identifieur interne : 000134 ( Main/Exploration ); précédent : 000133; suivant : 000135Linking groundwater pollution to the decay of 15th-century sculptures in Burgos Cathedral (northern Spain).
Auteurs : Fernando Gázquez [Royaume-Uni, Espagne] ; Fernando Rull [Espagne] ; Jesús Medina [Espagne] ; Aurelio Sanz-Arranz [Espagne] ; Carlos Sanz [Espagne]Source :
- Environmental science and pollution research international [ 1614-7499 ] ; 2015.
Descripteurs français
- KwdFr :
- Carbonate de calcium (analyse), Espagne (MeSH), Histoire du 15ème siècle (MeSH), Matériaux de construction (analyse), Minéraux (analyse), Nappe phréatique (analyse), Polluants chimiques de l'eau (analyse), Pollution de l'environnement (MeSH), Sculpture (histoire), Surveillance de l'environnement (MeSH).
- MESH :
English descriptors
- KwdEn :
- MESH :
- chemical , analysis : Calcium Carbonate, Minerals, Water Pollutants, Chemical.
- analysis : Construction Materials, Groundwater.
- history : Sculpture.
- Environmental Monitoring, Environmental Pollution, History, 15th Century, Spain.
Abstract
Precipitation of salts-mainly hydrated Mg-Na sulfates-in building materials is rated as one of the most severe threats to the preservation of our architectural and cultural heritage. Nevertheless, the origin of this pathology is still unknown in many cases. Proper identification of the cause of damage is crucial for correct planning of future restoration actions. The goal of this study is to identify the source of the degradation compounds that are affecting the 15th-century limestone sculptures that decorate the retro-choir of Burgos Cathedral (northern Spain). To this end, detailed characterization of minerals by in situ (Raman spectroscopy) and laboratory techniques (XRD, Raman and FTIR) was followed by major elements (ICP and IC) and isotopic analysis (δ(34)S and δ(15)N) of both the mineral phases precipitated on the retro-choir and the dissolved salts in groundwater in the vicinity of the cathedral. The results reveal unequivocal connection between the damage observed and capillary rise of salts-bearing water from the subsoil. The multianalytical methodology used is widely applicable to identify the origin of common affections suffered by historical buildings and masterpieces.
DOI: 10.1007/s11356-015-4754-6
PubMed: 26018286
Affiliations:
Links toward previous steps (curation, corpus...)
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C" first="Carlos" last="Sanz">Carlos Sanz</name><affiliation wicri:level="1"><nlm:affiliation>Arquitectura y Conservación de Monumentos, SL, 40002, Segovia, Spain. restcarlossanz@telefonica.net.</nlm:affiliation><country xml:lang="fr">Espagne</country><wicri:regionArea>Arquitectura y Conservación de Monumentos, SL, 40002, Segovia</wicri:regionArea><wicri:noRegion>Segovia</wicri:noRegion></affiliation></author></analytic><series><title level="j">Environmental science and pollution research international</title><idno type="eISSN">1614-7499</idno><imprint><date when="2015" type="published">2015</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Calcium Carbonate (analysis)</term><term>Construction Materials (analysis)</term><term>Environmental Monitoring (MeSH)</term><term>Environmental Pollution (MeSH)</term><term>Groundwater (analysis)</term><term>History, 15th Century (MeSH)</term><term>Minerals (analysis)</term><term>Sculpture (history)</term><term>Spain (MeSH)</term><term>Water Pollutants, Chemical (analysis)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Carbonate de calcium (analyse)</term><term>Espagne (MeSH)</term><term>Histoire du 15ème siècle (MeSH)</term><term>Matériaux de construction (analyse)</term><term>Minéraux (analyse)</term><term>Nappe phréatique (analyse)</term><term>Polluants chimiques de l'eau (analyse)</term><term>Pollution de l'environnement (MeSH)</term><term>Sculpture (histoire)</term><term>Surveillance de l'environnement (MeSH)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Calcium Carbonate</term><term>Minerals</term><term>Water Pollutants, Chemical</term></keywords><keywords scheme="MESH" qualifier="analyse" xml:lang="fr"><term>Carbonate de calcium</term><term>Matériaux de construction</term><term>Minéraux</term><term>Nappe phréatique</term><term>Polluants chimiques de l'eau</term></keywords><keywords scheme="MESH" qualifier="analysis" xml:lang="en"><term>Construction Materials</term><term>Groundwater</term></keywords><keywords scheme="MESH" qualifier="histoire" xml:lang="fr"><term>Sculpture</term></keywords><keywords scheme="MESH" qualifier="history" xml:lang="en"><term>Sculpture</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Environmental Monitoring</term><term>Environmental Pollution</term><term>History, 15th Century</term><term>Spain</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Espagne</term><term>Histoire du 15ème siècle</term><term>Pollution de l'environnement</term><term>Surveillance de l'environnement</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Precipitation of salts-mainly hydrated Mg-Na sulfates-in building materials is rated as one of the most severe threats to the preservation of our architectural and cultural heritage. Nevertheless, the origin of this pathology is still unknown in many cases. Proper identification of the cause of damage is crucial for correct planning of future restoration actions. The goal of this study is to identify the source of the degradation compounds that are affecting the 15th-century limestone sculptures that decorate the retro-choir of Burgos Cathedral (northern Spain). To this end, detailed characterization of minerals by in situ (Raman spectroscopy) and laboratory techniques (XRD, Raman and FTIR) was followed by major elements (ICP and IC) and isotopic analysis (δ(34)S and δ(15)N) of both the mineral phases precipitated on the retro-choir and the dissolved salts in groundwater in the vicinity of the cathedral. The results reveal unequivocal connection between the damage observed and capillary rise of salts-bearing water from the subsoil. The multianalytical methodology used is widely applicable to identify the origin of common affections suffered by historical buildings and masterpieces. </div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" IndexingMethod="Curated" Owner="NLM"><PMID Version="1">26018286</PMID><DateCompleted><Year>2016</Year><Month>06</Month><Day>06</Day></DateCompleted><DateRevised><Year>2018</Year><Month>12</Month><Day>02</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1614-7499</ISSN><JournalIssue CitedMedium="Internet"><Volume>22</Volume><Issue>20</Issue><PubDate><Year>2015</Year><Month>Oct</Month></PubDate></JournalIssue><Title>Environmental science and pollution research international</Title></Journal><ArticleTitle>Linking groundwater pollution to the decay of 15th-century sculptures in Burgos Cathedral (northern Spain).</ArticleTitle><Pagination><MedlinePgn>15677-89</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1007/s11356-015-4754-6</ELocationID><Abstract><AbstractText>Precipitation of salts-mainly hydrated Mg-Na sulfates-in building materials is rated as one of the most severe threats to the preservation of our architectural and cultural heritage. Nevertheless, the origin of this pathology is still unknown in many cases. Proper identification of the cause of damage is crucial for correct planning of future restoration actions. The goal of this study is to identify the source of the degradation compounds that are affecting the 15th-century limestone sculptures that decorate the retro-choir of Burgos Cathedral (northern Spain). To this end, detailed characterization of minerals by in situ (Raman spectroscopy) and laboratory techniques (XRD, Raman and FTIR) was followed by major elements (ICP and IC) and isotopic analysis (δ(34)S and δ(15)N) of both the mineral phases precipitated on the retro-choir and the dissolved salts in groundwater in the vicinity of the cathedral. The results reveal unequivocal connection between the damage observed and capillary rise of salts-bearing water from the subsoil. The multianalytical methodology used is widely applicable to identify the origin of common affections suffered by historical buildings and masterpieces. </AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Gázquez</LastName><ForeName>Fernando</ForeName><Initials>F</Initials><AffiliationInfo><Affiliation>Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge, Cambridgeshire, CB2 3EQ, UK. f.gazquez@ual.es.</Affiliation></AffiliationInfo><AffiliationInfo><Affiliation>Department of Condensed Matter Physics, Crystallography and Mineralogy, University of Valladolid, Paseo de Belén, 7, 47011, Valladolid, Spain. f.gazquez@ual.es.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Rull</LastName><ForeName>Fernando</ForeName><Initials>F</Initials><AffiliationInfo><Affiliation>Department of Condensed Matter Physics, Crystallography and Mineralogy, University of Valladolid, Paseo de Belén, 7, 47011, Valladolid, Spain. rull@fmc.uva.es.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Medina</LastName><ForeName>Jesús</ForeName><Initials>J</Initials><AffiliationInfo><Affiliation>Department of Condensed Matter Physics, Crystallography and Mineralogy, University of Valladolid, Paseo de Belén, 7, 47011, Valladolid, Spain. medina@fmc.uva.es.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Sanz-Arranz</LastName><ForeName>Aurelio</ForeName><Initials>A</Initials><AffiliationInfo><Affiliation>Department of Condensed Matter Physics, Crystallography and Mineralogy, University of Valladolid, Paseo de Belén, 7, 47011, Valladolid, Spain. jausanz@gmail.com.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Sanz</LastName><ForeName>Carlos</ForeName><Initials>C</Initials><AffiliationInfo><Affiliation>Arquitectura y Conservación de Monumentos, SL, 40002, Segovia, Spain. restcarlossanz@telefonica.net.</Affiliation></AffiliationInfo></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016456">Historical Article</PublicationType><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2015</Year><Month>05</Month><Day>29</Day></ArticleDate></Article><MedlineJournalInfo><Country>Germany</Country><MedlineTA>Environ Sci Pollut Res Int</MedlineTA><NlmUniqueID>9441769</NlmUniqueID><ISSNLinking>0944-1344</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D008903">Minerals</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D014874">Water Pollutants, Chemical</NameOfSubstance></Chemical><Chemical><RegistryNumber>H0G9379FGK</RegistryNumber><NameOfSubstance UI="D002119">Calcium Carbonate</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D002119" MajorTopicYN="N">Calcium Carbonate</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D003252" MajorTopicYN="N">Construction Materials</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D004784" MajorTopicYN="N">Environmental Monitoring</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D004787" MajorTopicYN="N">Environmental Pollution</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D060587" MajorTopicYN="N">Groundwater</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D049668" MajorTopicYN="N">History, 15th Century</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D008903" MajorTopicYN="N">Minerals</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D012613" MajorTopicYN="Y">Sculpture</DescriptorName><QualifierName UI="Q000266" MajorTopicYN="N">history</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D013030" MajorTopicYN="N">Spain</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D014874" MajorTopicYN="N">Water Pollutants, Chemical</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading></MeshHeadingList><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">ATR</Keyword><Keyword MajorTopicYN="N">Burgos Cathedral</Keyword><Keyword MajorTopicYN="N">Efflorescences</Keyword><Keyword MajorTopicYN="N">Groundwater pollutants</Keyword><Keyword MajorTopicYN="N">Raman spectroscopy</Keyword><Keyword MajorTopicYN="N">Stable isotopes</Keyword><Keyword MajorTopicYN="N">XRD</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2015</Year><Month>02</Month><Day>09</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2015</Year><Month>05</Month><Day>18</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2015</Year><Month>5</Month><Day>29</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2015</Year><Month>5</Month><Day>29</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2016</Year><Month>6</Month><Day>9</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">26018286</ArticleId><ArticleId IdType="doi">10.1007/s11356-015-4754-6</ArticleId><ArticleId IdType="pii">10.1007/s11356-015-4754-6</ArticleId></ArticleIdList><ReferenceList><Reference><Citation>Acc Chem Res. 2010 Jun 15;43(6):897-905</Citation><ArticleIdList><ArticleId IdType="pubmed">20214404</ArticleId></ArticleIdList></Reference><Reference><Citation>Sci Total Environ. 2013 Mar 1;447:403-14</Citation><ArticleIdList><ArticleId IdType="pubmed">23410862</ArticleId></ArticleIdList></Reference><Reference><Citation>Nat Commun. 2014 Sep 11;5:4823</Citation><ArticleIdList><ArticleId IdType="pubmed">25208600</ArticleId></ArticleIdList></Reference></ReferenceList></PubmedData></pubmed><affiliations><list><country><li>Espagne</li><li>Royaume-Uni</li></country><region><li>Angleterre</li><li>Angleterre de l'Est</li></region><settlement><li>Cambridge</li></settlement><orgName><li>Université de Cambridge</li></orgName></list><tree><country name="Royaume-Uni"><region name="Angleterre"><name sortKey="Gazquez, Fernando" sort="Gazquez, Fernando" uniqKey="Gazquez F" first="Fernando" last="Gázquez">Fernando Gázquez</name></region></country><country name="Espagne"><noRegion><name sortKey="Gazquez, Fernando" sort="Gazquez, Fernando" uniqKey="Gazquez F" first="Fernando" last="Gázquez">Fernando Gázquez</name></noRegion><name sortKey="Medina, Jesus" sort="Medina, Jesus" uniqKey="Medina J" first="Jesús" last="Medina">Jesús Medina</name><name sortKey="Rull, Fernando" sort="Rull, Fernando" uniqKey="Rull F" first="Fernando" last="Rull">Fernando Rull</name><name sortKey="Sanz Arranz, Aurelio" sort="Sanz Arranz, Aurelio" uniqKey="Sanz Arranz A" first="Aurelio" last="Sanz-Arranz">Aurelio Sanz-Arranz</name><name sortKey="Sanz, Carlos" sort="Sanz, Carlos" uniqKey="Sanz C" first="Carlos" last="Sanz">Carlos Sanz</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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